Seal and Gasket Elastomer Materials
Seal Dynamics is a custom manufacturer of gaskets using EPDM, Fluorel and VITON® gasket materials.
Ethlyene-Propylene, EP, En or EPDM
Ethlyene-propylene (EPDM) compounds are prepared from ethylene and propylene and usually a third monomer. These compounds are used frequently to seal phosphate ester fire resistant hydraulic fluids such as Skydrol. They are also very effective in brake systems, and for sealing hot water and steam. Ethylene-propylene compounds have good resistance to mild acids, alkalis, silicone oils and greases, ketones, and alcohols. They are not recommended for petroleum oils or di-ester lubricants. Ethylene-propylene has a temperature range of -67ºF to 302ºF (-55ºC to 150ºC). It is compatible with polar fluids that adversely affect other elastomers.
Advantages:
Excellent weather resistance
Good low temperature flexibility
Excellent chemical resistance
Good heat resistance
Disadvantage:
Poor petroleum oil and solvent resistance
Nitrite, Buna N, or NBR
Nitrite is the most widely used elastomer in the seal Industry. The popularity of nitrite is due to its excellent resistance to petroleum products and its ability to be compounded for service over a temperature range of -67ºF to 257ºF (-55ºC to 125ºC).
Nitrite is a copolymer of butadiene and acrylonitrile. Variation in proportions of these polymers is possible to accommodate specific requirements. An increase in acrylonitrile content increases resistance to heat plus petroleum base oils and fuels but decreases low temperature flexibility. Military AN and MS O-ring specifications require nitrite compounds with low acrylonitrile content to insure low temperature performance.
Nitrite provides excellent compression set, tear, and abrasion resistance. The major limiting properties of nitrite are its poor ozone and weather resistance and moderate heat resistance.
Advantages:
Good balance of desirable properties
Excellent oil and fuel resistance
Good water resistance
Disadvantages:
Poor weather resistance
Moderate heat resistance
Polyurethane, AU, or EU
Polyurethane compounds exhibit outstanding tensile strength and abrasion resistance in comparison with other elastomers. Fluid compatibility is similar to that of nitrite at temperatures up to approximately 158ºF (70ºC). At higher temperatures, polyurethane has a tendency to soften and lose both strength and fluid resistance advantages over other elastomers. Some types are readily damaged by water, even high humidity. Polyurethane seals offer outstanding performance in high pressure hydraulic systems with abrasive contamination, high shock loads, and related adverse conditions provided temperature is below 158ºF (70ºC).
Advantages:
Excellent strength and abrasion resistance
Good resistance to petroleum oils
Good weather resistance
Disadvantages:
Poor resistance to water
Poor high temperature capabilities
Chloroprene, Neoprene, or CR
Neoprene is a polymer of chlorobutadiene and is unusual In that it is moderately resistant to both petroleum oils and weather (ozone, sunlight, oxygen). This qualifies neoprene for O-ring service where many other elastomers would not be satisfactory. It is also used extensively for sealing refrigeration fluids. Neoprene has good compression set characteristics and a temperature range of -67"F to 284ºF (-55ºC to 140ºC).
Advantages:
Moderate weather resistance
Moderate 0 resistance
Versatile
Disadvantage;
Moderate solvent and water resistance
Fluorocarbon, Viton, Fluorel, or FKM
Fluorocarbon combines resistance to a broader range of chemicals than any of the other elastomers. It constitutes the closest available approach to the universal O-ring elastomer. Although most fluorocarbon compounds become quite hard at temperatures below -4ºF (-20ºC), they do not easily fracture, so they are serviceable at much lower temperatures. Fluorocarbon compounds provide a continuous 437"F (225ºC) high temperature capability.
Advantages:
Excellent chemical resistance
Excellent heat resistance
Good mechanical properties
Good compression set resistance
Disadvantage:
Fair low temperature resistance
Fluorosilicone or FVMQ
Fluorosilicones combine most of the attributes of silicone with resistance to petroleum oils and hydrocarbon fuels. Low physical strength and abrasion resistance combined with high friction limit fluorosilicone to static seals. Fluorosilicones are used primarily in aircraft fuel systems over a temperature range of -85ºF to 347ºF (-65ºC to 175ºC).
Advantages:
Excellent at temperature extremes
Good resistance to petroleum oils and fuels
Good compression set resistance
Disadvantage:
Poor physical strength
If you are looking for VITON gaskets or EPDM gaskets feel free to contact Seal Dynamics to get more information about how we use EPDM and VITON in our process.
Hydrogenated Nitrile (HNBR)
Hydrogenated nitrile is a synthetic polymer that results from the hydrogenation of nitrile rubber (NBR). In this process the molecular "double bonds" in the NBR primary polymer chain undergo a hydrogenation process and therefore the term "hydrogenated nitrile" (HNBR). The allowable temperature range extends to 149ºC (300ºF) with short periods at higher temperature possible. By following design guidelines effective sealing can be achieved at -32ºC (-25ºF) for static applications. For dynamic applications however, operating temperatures are limited to above 23ºC (-10ºF). HNBR compounds possess superior mechanical characteristics, particularly their high strength. For sealing applications up to approximately 159ºC (300ºF), this is an advantage as it prevents extrusion and wear.
Chemical resistance
Aliphatic hydrocarbons
Vegetable and animal fats and oils
HFA, HFB and HFC fluids
Dilute acids, bases and salt solutions at moderate temperatures
Water and steam up to 159ºC (300ºF)
Ozone, aging and weathering
Not compatible with:
Chlorinated hydrocarbons
Polar solvents (ketone and ester)
Strong acids
Perfluoroelastomer (FFKM)
The name "perfluoroelastomer" is somewhat misleading. An actual perfluorinated material with a high molecular weight is polytetrafluoroethylene or PTFE. The molecular carbon chain is shielded by the chemical inertness of the large bonded fluorine atoms. Perfluoroelastomer is produced by the copolymerization of tetrafluoroethylene (TFE) and a perfluorinated ether, e.g. perfluoromethylvinylether (PMVE).
The differing resistance to volume swell of the different perfluoroelastomers is due to the perfluorinated ether element, where the side-chain can consist of up to four perfluorinated carbon atoms. The extraordinary chemical resistance is partly due to the fluorine atoms shielding the carbon chain, and partially due to the vulcanization system.
Heat resistance
232ºC to 300ºC (450ºF to 590ºF) depending on compound.
Cold flexibility
-18ºC to -26ºC (0ºF to -15ºF)
Chemical resistance
Aliphatic and aromatic hydrocarbons
Chlorinated hydrocarbons
Polar solvents (acetone, methylethylketone, ethylacetate, diethylether and dioxane)
Inorganic and organic acids
Water and steam
High vacuum with minimal loss in weight
Not compatible with:
Fluorinated refrigerants (R11, 12, 13, 113, 114, etc.)
Silicone or PVMQ
Silicone is a semi-organic elastomer with outstanding resistance to extremes of temperature. Specially compounded, it can provide reliable service at temperatures as low as -75ºF (-59ºC) to as high as 450ºF (232ºC) continuously. Silicone also has good resistance to compression set.
Low physical strength and abrasion resistance combined with high friction limit silicone to static seals. Silicone is used primarily for dry heat static seals. Although it swells considerably in petroleum lubricants, this is not detrimental in most static sealing applications.
Advantages:
Excellent at temperature extremes
Excellent compression set resistance
Disadvantage:
Poor physical strength
Seal Dynamics is a custom manufacturer of gaskets using EPDM, Fluorel and VITON gasket materials. Contact us if you would like more information.
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